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Physical Properties

About RMC3000/3080 , The physical and chemical properties are listed in Table 1 C Physical Properties.

Iedntification
The detection and determination of methylcyclopentadienyl manganese tricarbonyl is achieved by gas chromatography, spectroscopy, and titration.

Chemical Structure
Methylcyclopentadienyl manganese tricarbonyl is an organometallic compound a central manganese coordinated between a methylcyclopentadienyl group and (3) carbon monoxide groups. A jmol model is shown below.

Table 1 C Physical Properties.

 

RMC 3000

RMC 3080

Formula

C9H7O3Mn

C9H7O3Mn

CAS No.

12108-13-3

12108-13-3

ACX No.

X1003193-3

X1003193-3

RTECS No.

OP14500000

OP14500000

Mn Content (wt%)

15.10

20.08

Appearance

Translucent
Liquid

Translucent
Liquid

Color

Orange

Orange

SG@20

1.11

1.23

Flash Point
(
H TCC)

104

125

Water Solubility
25
(g/L)

0.027

0.029

The following IR spectra was produced.

Photolysis
Methylcyclopentadienyl manganess trcarbonyl undergoes photolysis in sunlight. The reaction kinetics of a solution of methylcyclopentadienyl manganese tricarbonyl in gasoline at a concentration of 0.15 g/l manganese indicate a half-life of approx, 40 minutes as shown in the following data:

Table 2 C Photolysis

Time (mins)

Mn Concentration
(mg g/l)

10

0.0121

20

0.0092

30

0.0834

40

0.0685

50

0.0440

60

0.0319

Conclusion

RMC3000/3080  are solutions of methylcyclopentadienyl manganese tricarbonyl, CAS 12108-13-3. no significant impurities or heavy metals were detected on analysis. Samples were devoid of impurities, and are suitable for fuel blending without modification.


RMC3000/3080 is an organic manganese compound designed to boost octane levels in gasoline at an economical cost.  In addition, when used at very low levels in diesel fuel, it is a very effective smoke suppressant.  Scientists at Ethyl Corporation developed it in the 1950s to reduce common engine knock in automobiles.  The product has been manufactured and marketed by Ethyl for more than twenty years.  It has been sold in Canada from the outset, and is currently used in the United States, Europe, Asia, Australia, as well as Central and South America.

RMC3000/3080 provides a number of scientifically documented environmental benefits while posing no harm to automotive emission systems or human health.  When added to gasoline at the refinery level, it helps reduce refinery emissions of carbon dioxide, a greenhouse gas that has been linked to global warming.  When used in unleaded gasoline, RMC3000/3080 can reduce exhaust pollutants such as oxides of nitrogen and carbon monoxide, known contributors to urban smog. The US EPA has acknowledged that vehicles using unleaded gasoline containing RMC3000 average 15-20% lower tailpipe emissions of oxides of nitrogen (NOx).

RMC3000/3080 is one of the most comprehensively tested fuel additives in history.  When used as directed it is completely compatible with modern emission control systems, and has no known adverse human health effects.  The long-term effect of manganese exposure has been studied for decades and continues.  These studies, including one completed in 1998 by the Research Triangle Institute (RTI) of North Carolina, support the existing scientific evidence that RMC3000/3080 poses no health risk.

Because RMC3000/3080 is a fuel additive, a number of government and environmental regulations apply to the product's continued safe use and distribution.  Over the last 10 years, Ethyl Corporation has worked with governments around the world and has sponsored numerous scientifically designed vehicle and personal exposure analyses through internal and independent test facilities. Today, scientific data accumulated over more than 10 million miles of driving proves RMC3000/3080 is safe and effective for use in unleaded gasoline and diesel fuels.

RMC has developed RMC3000/3080 based formulations for a wide variety of applications. 

Some of these products are registered with the US EPA for domestic on-highway applications.  Others are intended for similar use in countries where gasoline octane quality is low, while others are specifically designed for high performance  off-road or racing applications.  Finally, with the imminent worldwide phase out of leaded gasoline, an opportunity has arisen for an RMC3000/3080 based formulation to provide protection against valve seat recession (VSR), in the very large number of vehicles, many of which are classics, which were designed to use leaded gasoline.  In the latter category, we have a formulation that is officially approved by the Federation of British Historic Vehicle Clubs.

Description

RMC3000/3080 is an octane booster and emissions reducer for unleaded gasoline.

Use Information

Add to unleaded gasoline at the required dosage rate of between 8 to 18 mg Mn/liter
(0.024 to 0.053 ml RMC3000-3080 / liter unleaded gasoline).

Features Physical Data (typical properties)

The most cost-effective additive for increasing octane in unleaded gasoline.
Effective in reducing tailpipe NOx emissions.
Enables refiners to reduce refining severity and aromatic content.
Saves crude oil and increases refinery yield.
Compatible with all internal combustion engines and catalytic converters.
Compatible with oxygenates.
Stable during storage.
Low freezing point.

Appearance: ........................................................Orange Liquid
Density (lb/gal @ 20C):................................................ 9.09/10
Flash Point (C, TCC)..................................52/(125
H/41 (104 ºF)
Freezing Point (F):.................................. -30(-22
H/.-15 (15 ºF)
Gm Mn/liter............................168(635g/us gal/337 (1277 g/US gal)
Gm Mn/kilogram..................................151(68.6g/lb)/244 (111 g/lb)
Manganese content (wt%)......................................15.1/20.8 min.
Specific Gravity (20C):...............................................1.11/1.25
Vapor Pressure (mmHg @20C):........................................1.6/1.6

Handling Information

Ecotane® 3000 is toxic by inhalation, ingestion, and skin contact.  Ecotane® is extremely photosensitive and decomposes rapidly when exposed to light. The half-life of Ecotane® vapor in air is less than one minute when exposed to light. Photolytic action converts the organic compound to a mixture of non-hazardous manganese oxides, carbonates, and organics derived from methylcyclopentadiene.  See MSDS for further information.

Transportation Data

Standard Containers:..............Tank trailers, ISO tanks, drums (55 gal UN lined steel)
Net Drum Weight (pounds): ....625 (55 gal drums)
HMIS Rating:...........................Health=3  Flammability=2 Reactivity=0, Personal Protective Equipment=C
NFPA Rating: ..........................Health=2  Flammability=2 Reactivity=1
Shipping Name (DOT): ...........Metal carbonyls, n.o.s., liquid (methylcyclopentadienyl manganese tricarbonyl),

6.1, UN3281, PG II. Shipping Name (IMO): ............Metal carbonyls, n.o.s., liquid (methylcyclopentadienyl manganese tricarbonyl), 6.1, UN3281, PG II, MARINE POLLUTANT. Shipping Name (IATA):...........Metal carbonyls, n.o.s., liquid (methylcyclopentadienyl manganese tricarbonyl), 6.1, UN3281, PG II.

MSDS and Emergency Response Information

Contact US RMC Energy during normal business hours for further information and to obtain a current Material Safety Data Sheet. For 24 hour emergency response instructions or to receive a MSDS via fax after hours, contact US RMC Energy at 314.255.6424.

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